Coulometric Titration with Electrogenerated Tin(II). Titration of Platinum(IV)
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Evaluation of the stability of iron(II) solutions by precise coulometric titration with electrogenerated cerium(IV).
An iron(II) solution is often used as a reducing agent in titrimetry and standardized with cerium(IV) or potassium dichromate. Such an iron(II) standard solution is needed for not only titrimetric analyses, but also instrumental ones. Iron(II) is unstable even in a highly acidic solution, mainly due to air-oxidation; therefore, its standardization is required before use. In the present study...
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Although the roster of coulometric titrations no\\' includes many reactions of classical titrimetry'. the lIse of cl,ectrogeneratecl +2 tin as a coulometric titrant has not previously been reported. We have found that in an acidic bromide medium +4 tin (probably SrlBr6-2) is reduced to the' +2 state (probably SnBr4-2) with 100% current efficiency' at a gold cathode. The formal potential of the ...
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